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Last update of this
page : 30/06/2004
Reduction techniques and costs
Nitrogen
oxides (NOx)
Any combustion in air (boilers, car
engines, cigarettes etc.) causes nitrogen oxide emissions. These
NOx emissions are the result of reactions between the nitrogen (from
the air or the fuel) and the oxygen in the air.
The two main sources of NOx emissions
are the internal combustion engine and stationary combustion plants.
If catalytic converters are fitted
to vehicles, they limit NOx emissions. As for combustion plants,
two types of technique exist: primary techniques
(acting on combustion) and secondary techniques
(acting on the waste gases).
Primary techniques
These limit
emissions by acting on combustion. For instance, there are low-NOx
burners, recycling of combustion gases, gradual injection of the
fuel and/or the combustion air. The effectiveness of these techniques
varies between 20 and 60% (if several primary techniques are combined).

Secondary techniques
These yield
far higher reduction rates. Only the two processes which have really
made an impact on the market are indicated here.
Selective
non catalytic reduction (SNCR)
NOx
are reduced by the action of urea or ammonia, injected into the
furnace without a catalyser. In this case, the reaction occurs at
high temperature (850-1050°C).
The efficiency is between 50 and 70% with an NH3/NO ratio of 2.5.
Selective
catalytic reduction (SCR)
This works
on the combustion gases by the reducing action of ammonia at 280-400°C
in the presence of a catalyser.
This type of process can reduce the NOx content of the fumes by
up to 90% with an NH3/NO ratio of 0.7-1.
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Investment
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Operating
cost
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Efficiency
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SCR
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90%
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SNCR
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50-70%
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Orders
of magnitude concerning the cost of these processes
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